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61.
Study of the effect of vintage,maturity degree,and irrigation on the amino acid and biogenic amine content of a white wine from the Verdejo variety 下载免费PDF全文
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Sonia EscolásticoCecilia Solís José M. Serra 《International Journal of Hydrogen Energy》2011,36(18):11946-11954
This contribution presents the preparation, permeation and stability study of mixed protonic-electronic conducting membranes based on the system Nd5LnWO12. The tungstates Ln6WO12 are proton conducting crystalline materials, which show sufficient protonic and electronic mixed conductivity and stability in moist CO2 environments to consider them as potential candidates for the separation of hydrogen at high temperatures. Hydrogen separation properties of A-substoichiometric Nd6WO12 and Nd5LaWO12 were systematically analyzed, i.e. the influence of the H2 concentration in feed stream, humidification degree and operating temperature on the hydrogen separation was studied. Finally, the stability of these materials at different temperatures and CO2-rich and sulfur-containing environments was evaluated. 相似文献
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In many of the continuum processes typically found in chemical engineering, the functional dependency of the dependent variable is only known for large and small values of the independent variable. Exact solutions in the transitional regime are often obscure for various reasons (e.g. narrow band within which the transition from one regime to the other occurs, inadequate knowledge of the physics in this area, etc.). An established method for the matching of limiting solutions is reviewed and subsequently applied. The method regards the known solutions as asymptotes and proposes addition to a power of such asymptotes. It yields a single, adjustable correlating equation that is applicable over the entire domain. This procedure circumvents the introduction of ad hoc curve fitting measures for the different regions and subsequent, unwanted discontinuities in piece-wise fitted correlative equations for the dependent variables. Experimental data of two diverse processes, namely flow in a straight-through diaphragm valve and the fluidisation of a packed bed, are analysed as case studies. Empirical results are investigated for possible asymptotic bounds whereafter power addition is applied to the functional dependencies. The outcome is compared to those of the empirical models and the results discussed. The procedure is revealed to be highly useful in the summarising and interpretation of experimental data in an elegant and simplistic manner. It may also, in general, aid the setup of experimental apparatus for investigation of continuum processes. 相似文献
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Luisa Barba Gianmichele Arrighetti Sonia Calligaris 《European Journal of Lipid Science and Technology》2013,115(3):322-329
Crystallization and melting properties of triacylglycerols in extra virgin olive oil were studied by using synchrotron X‐ray diffraction (XRD) and differential scanning calorimetry (DSC). The phase transitions were monitored by cooling and heating the samples at 2°C/min from 60 to ?60°C and vice versa. Upon cooling, a first DSC endothermic peak was recorded at ?9.6°C followed by one at ?33.5°C. These thermal events were associated to the formation of two different structures: a triple‐chain length (3L) having a c parameter of about 58.38 Å and a quadruple chain length structure (4L) with a c parameter of about 89.99 Å, respectively. Both structures evidenced a cell packing arrangement ascribable to a β′ form. During heating, part of the metastable β′ crystals rearranged into the more thermodynamically stable β form. Then, upon further heating, the sequential melting of the two crystal structures was observed. The melting was completed at 10.7°C. Beside this interpretation of XRD data, a model considering a cell with a c parameter of about 170 Å and a hexagonal crystal system was proposed. Even if more research is needed to validate this approach, it allowed all XRD events recorded during the experiments to be described. See commentary by Chiavaro [p. 267–269], http://dx.doi.org/10.1002/ejlt.201200415 相似文献
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Some contractor selection methods currently in existence are criticized as incomplete and biased, and lacking consideration in terms of the contractor's ability to achieve simultaneously, time, cost, quality and safety standards. This research examines an alternative contractor selection model called the analytical hierarchy process (AHP), which will help construction clients to identify contractors with the best potential to deliver satisfactory outcomes in a final contractor selection process which is not based simply on the lowest bid. The AHP comprises three parts: hierarchic structure, prioritization procedure, and calculation of results. This model is tested by a hypothetical scenario where three contractor candidates are evaluated. The criteria used for contractor selection in the model have been identified, and the significance of each criterion has been arrived at by conducting a questionnaire survey in public organizations in Hong Kong. Comparisons are made by ranking the aggregate scores of each candidate with regard to their performance against each of the criteria, and the candidate associated with the highest scores is the best contractor on this occasion. 相似文献
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Sonia Hirt 《Journal of the American Planning Association. American Planning Association》2013,79(4):436-450
Problem: Traditional American zoning separates land uses, yet many urbanists and contemporary planners argue that bringing mixed use back to the American city is the key to restoring its vibrancy. Purpose: This article compares the American and the German approaches to regulating land use. Methods: I derive my conclusions from a review of German federal and local regulatory documents, and interviews I conducted in the German city of Stuttgart. Results and conclusions: The U.S. zoning approach assumes that each land use district is suitable for only a single type of human activity, such as residential, commercial, or industrial use; whereas in Germany the prevailing principle is that each land use district is suitable for multiple types of activity, and most districts end up in mixed uses. Thus, despite some nominal similarities in the land use categories employed in both countries, the zoning methods are in fact starkly different. Takeaway for practice: The German zoning system, which commonly mixes the land uses, challenges deeply engrained assumptions that underlie standard U.S. zoning, and it may offer useful alternatives for zoning reform. 相似文献
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Ferreri C Manco I Faraone-Mennella MR Torreggiani A Tamba M Manara S Chatgilialoglu C 《Chembiochem : a European journal of chemical biology》2006,7(11):1738-1744
The occurrence of tandem damage, due to reductive radical stress involving proteins and lipids, is shown by using a biomimetic model. It is made of unsaturated lipid vesicle suspensions in phosphate buffer in the presence of methionine, either as a single amino acid or as part of a protein such as RNase A, which contains four methionine residues. The radical process starts with the formation of H(.) atoms by reaction of solvated electrons with dihydrogen phosphate anions, which selectively attack the thioether function of methionine. The modification of methionine to alpha-aminobutyric acid is accompanied by the formation of thiyl radicals, which in turn cause the isomerization of the cis fatty acid residues to the trans isomers. The relationship between methionine modification and lipid damage and some details of the reductive radical stress obtained by proteomic analysis of irradiated RNase A are presented. 相似文献